Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 2, Pages 302-304Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2003.12.001
Keywords
Ce3+; photoluminescence; haloapatites; charge compensation
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The luminescence properties of Ce3+ ions in calcium halophosphates Ca-5(PO4)(3)X (X = F, Cl) has been studied. The excitation bands of Ca5-2xCexNax(PO4)(3)Cl are shifted to lower energies comparing with Ca5-2xCexNax(PO4)(3)F. Codoping with Na+ ions results in a remarkably increase of the luminescence intensity of Ce3+-doped Ca-5(PO4)(3)X apatites due to the charge compensation. (C) 2003 Elsevier B.V. All rights reserved.
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