Journal
ADVANCED MATERIALS
Volume 16, Issue 3, Pages 226-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200304906
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A simple process of solvent evaporation is shown to produce highly ordered arrays of cylindrical microdomains in block copolymers with long-range lateral order (see Figure). Solvent evaporation in thin films is unidirectional, producing a self-assembly directed normal to the film surface, akin to a zone refinement. Further control over the size and separation distance of the domains can be achieved with cosolvents.
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