Journal
ORGANIC LETTERS
Volume 6, Issue 3, Pages 353-355Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol036190a
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Alkynyl imines underwent [4 + 2] electrocyclization in the presence of 20 mol % W(CO)(5)(THF) to give 2-arylated quinolines in good yields. A deuterium labeling study suggests that the reaction proceeds via a tungsten vinylidene complex.
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