Journal
CHEMICAL PHYSICS LETTERS
Volume 385, Issue 5-6, Pages 449-455Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2003.12.113
Keywords
-
Ask authors/readers for more resources
We present a critical evaluation of the kinetic energy released in the unimolecular dissociation of C-60(+), C-58(+), and C-56(+). High-quality kinetic energy release distributions (KERD) have been recorded in a three-sector-field mass spectrometer that is equipped with two electric sectors. Systematic errors arising from assumptions about the shape of the KERD are explored by a combination of experiments and simulations; an alternative to the 'model-free approach' is suggested. For decay of C-60(+), an average KER of 394 +/- 14 meV is obtained. Surprisingly, the experimental KER distributions are virtually indistinguishable from the one expected for a pure Langevin-type interaction. (C) 2004 Published by Elsevier B.V.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available