Journal
ORGANIC LETTERS
Volume 6, Issue 4, Pages 601-603Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol036391e
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Treatment of diphenyl disulfide and terminal alkynes with gallium trichloride afforded (E)-1,2-diphenylthio-1-alkenes selectively (E/Z > 20/1). Alkenes also underwent this reaction to form trans adducts.
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