4.4 Article

Interesting by-products in the synthesis of chiral α-aminophosphinates from enantiopure sulfinimines

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 9, Pages 1991-1994

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2003.12.151

Keywords

alpha-aminophosphinic acids; ethyl phenylphosphonic acid; side reaction of p-tolylsulfinimines

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A new reaction of enantiopure sulfinimines and ethyl phenylphosphinate is given. Several unexpected products were isolated and identified, their mechanism of formation is proposed. (C) 2004 Elsevier Ltd. All rights reserved.

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