4.5 Article

(NHC)CuI (NHC = N-heterocyclic carbene) complexes as efficient catalysts for the reduction of carbonyl compounds

Journal

ORGANOMETALLICS
Volume 23, Issue 5, Pages 1157-1160

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om034285a

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The hydrosilylation of various ketones is mediated by an imidazolium salt/ Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.

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