Journal
TETRAHEDRON
Volume 60, Issue 10, Pages 2427-2432Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2003.12.051
Keywords
porphyrin; N-confused porphyrin; N-confused dipyrromethane; Cu(III); Ag(III)
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A(2)B(2) type of cis-doubly N-confused porphyrins (cis-N2CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated. (C) 2004 Elsevier Ltd. All rights reserved.
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