4.3 Article

A simple method for the preparation of functionalized steric hindered methacrylic acid esters and amides

Journal

SYNTHETIC COMMUNICATIONS
Volume 34, Issue 5, Pages 767-774

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-120028349

Keywords

carbodiimides; methacrylamides; methacrylates; polymerization; phosphonic ester group; steric hindered esters

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Methacrylates are obtained by using a one pot method, in which the alpha-methyl substituted acrylic acid is converted into the corresponding anhydride in situ by means of carbodiimides or p-toluenesulfonyl chloride and a further reaction with 2,6-dialkylphenols in the presence of 4(dimethylamino)pyridine (DMAP) as the catalyst.

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