4.8 Article

Design, synthesis, and crystallographic studies of neutral platinum-based macrocycles formed via self-assembly

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 126, Issue 8, Pages 2464-2473

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja039235b

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Funding

  1. NIGMS NIH HHS [GM-57052] Funding Source: Medline

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A series of neutral, platinum-based macrocycles was synthesized from rigid oxygen donor building blocks via self-assembly. The combination of a platinum-based 60degrees acceptor unit 1 with several linear and angular dicarboxylate bridging ligands afforded hitherto unknown neutral platinum-based supramolecular triangles and rhomboids. In addition, a similar reaction of the diplatinum molecular clip 6 and three different linear dicarboxylates led to the formation of neutral molecular rectangles. Most of the macrocycles were characterized by X-ray single-crystal structure analysis, and, in all cases, NMR spectra were consistent with the formation of single highly symmetrical species.

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