4.7 Article

Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 5, Pages 512-513

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b315911f

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Novel cyclopropyl containing fatty acids are good substrates for P450(BM3) catalysed hydroxylation and analysis of their oxidation products indicates the presence of a radical intermediate (maximum rebound rate 2.6x10(10) s(-1)) and the absence of any cationic intermediate.

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