Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 211, Issue 1-2, Pages 17-21Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2003.10.004
Keywords
ligand; isomer; asymmetric cyclopropanations
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Novel chiral PN,N-type ligands (4) derived from (R)-(S)-PPFNH2-R (6) and 2-pyridinecarboxaldehydes were employed in Ru(II)-catalyzed asymmetric cyclopropanation of styrene with ethyl diazoacetate. Up to 99% yield with 95% e.e. for cis-isomer and 90% e.e. for trans-isomer was obtained on Ru(II)/4a. (C) 2003 Elsevier B.V. All rights reserved.
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