4.5 Article

Structurally characterized neutral monoalkyl and -aryl complexes of manganese(II)

Journal

ORGANOMETALLICS
Volume 23, Issue 6, Pages 1177-1179

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om030645i

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The synthesis and X-ray crystal structures of the monomethyl and -phenyl manganese complexes [LMn(mu-Me)](2) (2) and LMnPh (3) (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) are reported. These complexes represent the first structurally characterized neutral dimeric manganese(II) monoalkyl complexes and monomeric manganese(II) monoaryl complexes. Furthermore, compound 3 shows an interesting coplanar arrangement of the phenyl group and the chelating ligand.

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