Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 211, Issue 1-2, Pages 55-58Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2003.10.005
Keywords
ethylene polymerization; iron(II) complex; 2,6-bis(imino)pyridyl ligand
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The iron-based catalyst 2,6-bis[1-(4-bromo-2,6-dimethylphenylimino)ethyl]-pyridineiron(II) chloride, 1, has been successfully synthesized and characterized. Its catalytic activity was evaluated for the polymerization of ethylene at different temperatures and Al/Fe ratios and compared with that of 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridineiron(II) chloride, 2. The results show that the catalytic activity of catalyst 1 is highly dependent on the amount of MAO used in the polymerization of ethylene and presents a maximum value at about 20degreesC. (C) 2003 Elsevier B.V. All rights reserved.
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