4.4 Article

Sulfilimine palladacycles: stable and efficient catalysts for carbon-carbon coupling reactions

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 14, Pages 2915-2918

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.02.069

Keywords

sulfilimine palladacycle; Suzuki coupling reaction; Heck reaction; Sonogashira reaction

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A new family of sulfilimine-based palladacycles (1-4) has been synthesized in high yields from easily accessible starting materials and is found to exhibit high catalytic activities for carbon-carbon bond-formation in Suzuki, Heck, Sonogashira and Ullmann-type reactions, affording coupled products in excellent yields. (C) 2004 Elsevier Ltd. All rights reserved.

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