Journal
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 51, Issue 2, Pages 371-376Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.200400058
Keywords
isomerization; beta,gamma-unsaturated ketone; alpha,beta-unsaturated ketone; DBU
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A series of beta,gamma-unsaturated ketones were isomerized to their corresponding alpha,beta-unsaturated ketones by the introduction of DABCO in iPrOH at room temperature. The endo-cyclic double bond (beta,gamma-position) on ketone was rearranged to exo-cyclic double bond (alpha,beta -position) under the reaction conditions.
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