Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2004, Issue 8, Pages 1675-1692Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200300492
Keywords
thiacalixarenes; supramolecular chemistry; stereochemistry; X-ray diffraction
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Thiacalixarenes - new members of the calixarene family are very promising molecules with many potential applications in supramolecular chemistry. The presence of four sulfur atoms in the place of methylene groups imparts many novel features and properties to these molecules. This review deals with the chemistry of thiacalixarenes, and by comparision with classical calixarenes, emphasizes their differences in reactivity, unusual conformational preferences and modified complexation abilities. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
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