Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 4, Pages 463-466Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2003.12.022
Keywords
metal organic chemical vapor deposition (MOCVD); aminoalkoxide ligands; donor-functionalized ligands; monomeric complexes; crystal structure
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The fluorine free Cu(II) aminoalkoxide complexes Cu(OCMe2CH2NR2)(2) (R = Me(I), Et(II)) are synthesized and characterized as a low melting solid (I) and a viscous liquid (II). The complexes are thermally decomposed at below 200degreesC to produce metallic copper by unusual gamma-hydrogen elimination reaction. (C) 2003 Elsevier B.V. All rights reserved.
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