Journal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
Volume 60, Issue -, Pages 174-178Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108768104002678
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The bond-valence method, especially the valence-sum rule, is very useful for checking if the structures formed by trivalent lanthanides are correct. In this work bond-valence parameters (R-ij), which connect bond valences and bond lengths, have been computed for a large number of bonds taken from the Cambridge Structural Database, Version 5.24 (2002) [Allen (2002). Acta Cryst. B58, 380 - 388]. The calculated values of bond-valence parameters for metal-organic compounds decrease with an increase in lanthanide atomic number; the R-ij values are also smaller than bond-valence parameters calculated for inorganic compounds. A summary of bond-valence sums calculated for R-ij given in this work and reported in the literature, and a functional correlation between lanthanide - oxygen distances and coordination number are presented.
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