4.4 Article

A new highly chemoselective isomerization of allylamides

Journal

TETRAHEDRON
Volume 60, Issue 16, Pages 3575-3579

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.03.004

Keywords

enamide; iridium; isomerization

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This work describes the first iridium-catalyzed isomerization of N-allylamides into enamides. This strategy allows the chemoselective preparation of (E)-N-(1-propenyl)-enamides and can be applied for the selective deprotection of N-allylamides. (C) 2004 Elsevier Ltd. All rights reserved.

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