Journal
ORGANIC LETTERS
Volume 6, Issue 8, Pages 1237-1240Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0499203
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- NIGMS NIH HHS [GM 28384] Funding Source: Medline
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[GRAPHICS] After revisiting earlier works reporting the regioselective synthesis of 1,5-disubstituted-1,2,3-triazoles via the addition of bromomagnesium acetylides to azides, much improved yields of the products were obtained for a wide array of azides and alkynes. The intermediates of that reaction can be trapped with different electrophiles to regioselectively form 1,4,5-trisubstituted 1,2,3-triazoles.
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