Journal
ORGANIC LETTERS
Volume 6, Issue 9, Pages 1341-1344Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol036441f
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- NIGMS NIH HHS [GM57306] Funding Source: Medline
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The recognition of tripeptides by a metal-centered receptor consisting of a rigid backbone region and variable tripeptide arms is described. The studies showed that the receptor was selective for L-Xxx-L-Lys-L-Lys, with Xxx = His, Cys, and Met, giving association constants near 1.0 x 10(5) M-1. Binding enhancement through cooperative interactions of the peptidic arms is demonstrated.
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