Journal
ORGANIC LETTERS
Volume 6, Issue 9, Pages 1393-1396Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol049757b
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The demetalation of M-III(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)(2).
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