Journal
CHEMICAL ENGINEERING RESEARCH & DESIGN
Volume 82, Issue A5, Pages 667-681Publisher
INST CHEMICAL ENGINEERS
DOI: 10.1205/026387604323142739
Keywords
xylenes; faujasite zeolite; adsorption; equlibrium; kinetics; modelling
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The adsorption of p-xylene, o-xylene and ethylbenzene on ion-exchanged fuajasite type zeolite has been studied in liquid phase at 30, 50, 80, 120 and 180degreesC. The single adsorption isotherms have been measured in a batch mode. The Langmuir and Sips isotherm have been used to describe the experimental adsorption isotherm data. The Sips equation fits the experimental isotherm data better than the Langmuir model. The saturation adsorption capacity of the adsorbent was similar for all components (around 1 mol kg(-1)). The p-xylene is the more strongly adsorbed component followed by ethylbenzene and o-xylene. The heat of the adsorption was 27.2 kJ/mol(-1) for p-xylene, 20.3 kJ/mol(-1) for ethylbenzene and 18.5 kJ/mol(-1) for o-xylene. The kinetics of adsorption of p-xylene, o-xylene and ethylbenzene was also studied. The xylene uptake curves have been described by a mathematical model that accounts for the macropore and/or micropore diffusion as rate controlling mechanisms. It was found that, for temperatures lower than 80degreesC in the case of p-xylene and lower than 50degreesC for o-xylene and ethylbenzene, both macropore and micropore diffusion contribute to the rate of adsorption. At higher temperatures macropore diffusion is the rate-controlling mechanism.
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