4.4 Article

Methods for reactive oxygen species (ROS) detection in aqueous environments

Journal

AQUATIC SCIENCES
Volume 74, Issue 4, Pages 683-734

Publisher

SPRINGER BASEL AG
DOI: 10.1007/s00027-012-0251-x

Keywords

Radical; Singlet oxygen; Superoxide; Hydrogen peroxide; Hydroxyl; Carbonate; Transient; Analysis; Aquatic environment; Reactive oxygen species

Funding

  1. US National Science Foundation [OCE 0752473]
  2. College of Arts and Sciences at the University of South Carolina
  3. Office Of The Director
  4. EPSCoR [904155] Funding Source: National Science Foundation

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This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): O-1(2), O (2) (center dot-) /HOO center dot, H2O2, HO center dot, and CO (3) (center dot-) in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.

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