Journal
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Volume 65, Issue 5, Pages 981-993Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2003.11.020
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Immiscibility effects are suggested to be inherent in tellurite glasses with weak (low valence) cations. This hypothesis is used to explain the structural evolution of the x(Tl2O) + (1 - x)Te2O glass system as a function of the x value and during temperature-induced crystallisation processes. The results of Raman measurements support the hypothesis. (C) 2003 Elsevier Ltd. All rights reserved.
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