Journal
PHILOSOPHICAL MAGAZINE LETTERS
Volume 84, Issue 5, Pages 303-310Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/09500830410001675704
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A nonlinear kinetic law and its corresponding variational principle are developed for solid-state diffusion under a large thermodynamic driving force. These are used to model the sintering of spherical particles. It is demonstrated that the classical linear diffusion law significantly underpredicts the sintering rate for nanosized particles.
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