Journal
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Volume 65, Issue 5, Pages 1011-1014Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2003.10.060
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The total electrical conductivities at room temperature of Ag6PSe5Cl, Ag6PSe5Br, and Ag6PSe5I were found to be 2.0 x 10(-1), 5.6 x 10(-1), and 6.8 x 10(-4) S/cm, respectively. In the chloride and iodide compounds, the electronic contribution comprises approximately 1% of the total conductivity, although it exceeds 10% of the total conductivity in the bromide compound. Ag6PSe5CI and Ag6PSe5Br exhibit purely Arrhenius behavior throughout the temperature range 150-300 K. Ag6PSe5I exhibits a second-order anomaly in electrical conductivity at 324 K. (C) 2003 Elsevier Ltd. All rights reserved.
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