4.8 Review

The determination of trace metal pollutants in enviromental matrices using ion chromatography

Journal

ENVIRONMENT INTERNATIONAL
Volume 30, Issue 3, Pages 403-431

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.envint.2003.09.009

Keywords

ion chromatography; chelation; metal ions; hyphenation; ICP-MS; post-column reaction

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A review is presented detailing the development of ion chromatography (IC) as a selective analytical tool for the determination of toxic metals and their organic species in many environmental sample matrices. A brief outline of ion chromatographic principles, together with an overview of the stationary phases used to separate metals, namely ion exchangers, modified ion pair sorbents and chelating ion exchangers, and the methods for detecting metal ions including hyphenation with spectroscopy and sample preparation schemes are also given, prior to a critical examination of developed methods for various metals including arsenic, chromium, cadmium, lead, mercury, beryllium, aluminium and uranium since 1990. (C) 2003 Elsevier Ltd. All rights reserved.

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