4.5 Article

Synthesis and structure of 1-D heterometallic thiocyanato-bridged CuIIGdIII polymers with ferromagnetic properties

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 9, Pages 1808-1812

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200300957

Keywords

heterometallic complexes; copper; lanthanides; magnetic properties

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Reaction of the tetracoordinate CuLA and CuLB complexes with Gd(NCS)(3) leads to two unique one-dimensional {Cu-Gd}(n) thiocyanato-bridged (1) and hydrogen-bonded (11) polymers, depending on the periphery of the L-A and L-B ligands, with ferromagnetic properties. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

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