Journal
JOURNAL OF POWER SOURCES
Volume 130, Issue 1-2, Pages 275-280Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2003.12.014
Keywords
nanoconaposite anodes; HEMM; amorphous silicone; silicon carbide
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The Si-SiC nanocomposites were synthesized by high-energy mechanical milling (HEMM) using two different starting mixtures, Si:SiC = 1:2 and Si:C = 3:2. Both mixtures result in amorphous silicon and nanocrystalline silicon carbide as confirmed by XRD results. The Si-SiC nanocomposite Corresponding to Si:SiC = 1:2 obtained after milling for 30h shows a capacity as high as similar to370 mAh/g. The nanocomposite synthesized using HEMM for 24 h from a mixture corresponding to Si:C = 3:2 also exhibits a stable capacity of similar to370 mAh/g. Transmission electron microscopy (TEM) analysis shows that SiC nanocrystallites congruent to10 nm in size are distributed homogeneously within the nanocomposite. Electron energy-loss spectroscopy (EELS) maps of C suggests that SiC is uniformly present within the particles. (C) 2004 Elsevier B.V. All rights reserved.
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