Journal
TETRAHEDRON
Volume 60, Issue 20, Pages 4475-4480Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.02.063
Keywords
asymmetric catalysis; cyclization; rhodium; tropos
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A tropos rhodium(l) complex having skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric ene-type carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers or spiro-rings. (C) 2004 Elsevier Ltd. All rights reserved.
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