Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 689, Issue 10, Pages 1734-1738Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2004.01.025
Keywords
silylcyanation; CsF; TMSCN; ketone; silylethers; cyanohydrins
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An efficient method of addition of trimethylsilylcyanide to ketones by employing cesium fluoride as catalyst has been described. A variety of aromatic, aliphatic, cyclic and heterocyclic ketones have been converted into their corresponding trimethylsilyl ethers in excellent yield.
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