4.2 Article

Carbon-ferrier rearrangements in ionic liquids using Yb(OTf)3 as catalyst

Journal

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 214, Issue 1, Pages 133-136

Publisher

ELSEVIER
DOI: 10.1016/j.molcata.2003.10.063

Keywords

ionic liquids; Carbon-Ferrier rearrangement; ytterbium triflate; glycal

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The ionic liquids [bmim][BF4] and [bmim][NTf2] are used as efficient recyclable solvents in the ytterbium triflate catalysed carbon-Ferrier rearrangement of triacetyl glucal with allyl silanes, propargyl silane, and silyl enolethers. (C) 2004 Elsevier B.V. All rights reserved.

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