Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 10, Pages 1240-1241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b403491k
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The 1-phosphanorbornadiene-rhodium complex (Rh-PNBD) anchored on a mesostructured porous silica matrix is the first example of a rhodium center chelated by a phosphorus and an oxygen atom belonging to the anchoring siloxane moiety. These new hybrid silicas behave as very active recyclable hydrogenation catalysts, which combined with additional grafted amino functions allow efficiently driven one-pot bifunctionnal catalysis.
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