4.4 Article

Synthesis and catalytic activity of a fluorous-tagged TEMPO radical

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 22, Pages 4249-4251

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.04.021

Keywords

alcohols; aldehydes; ketones; oxidation; biphasic catalysis

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A fluorous-tagged TEMPO radical has been prepared and its catalytic activity in the chemoselective oxidation of alcohols to carbonyl compounds has been investigated. The new fluorous radical proved to be an efficient, selective and easily recoverable catalyst, which can be conveniently used in standard organic solvents and then isolated and recycled by fluorous liquid-liquid extraction. (C) 2004 Elsevier Ltd. All rights reserved.

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