4.5 Article

Amido pincer complexes of palladium: Synthesis, structure, and catalytic Heck reaction

Journal

ORGANOMETALLICS
Volume 23, Issue 11, Pages 2813-2816

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om049888g

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Palladium complexes containing an o-phenylene-derived amido diphosphine ligand efficiently catalyze the Heck olefination of a wide array of aryl halides, leading to extremely high turnover numbers of up to 4.5 x 10(7).

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