Journal
ANALYTICA CHIMICA ACTA
Volume 511, Issue 1, Pages 37-45Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2004.01.042
Keywords
wavelet transform; varying background; noise; near infrared spectroscopy
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A new hybrid algorithm is proposed to eliminate the varying background and noise simultaneously for multivariate calibration of near infrared (NIR) spectral signals. The method is based on the use of multi-resolution, which is one of the main advantages provided by wavelet transform. The signals are firstly split into different frequency components, which keep the same data points of the original signals. In conjunction with a modified uninformative variable elimination (mUVE) criterion, the new method can be used to remove the low-frequency varying background and the high-frequency noise simultaneously. The method is successfully applied to simulated spectral data set and experimental NIR spectral data. resulting in more parsimonious multivariate models with higher precision. In addition, the proposed strategy can be applied to other spectral signals as well. (C) 2004 Elsevier B.V. All rights reserved.
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