4.4 Article

Synthesis and structure of polyhydroxyl rigid triangular nano-macrocyclic imine having multiple hydrogen-bonding sites

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 22, Pages 4225-4227

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.04.015

Keywords

hydrogen bond; inclusion compound; macrocycle; molecular recognition; Schiff base

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42-Membered macrocyclic oligoimines based on the rigid biphenyl framework with 12 hydroxyl groups directing inward were synthesized by six-component cyclization without using a template. In the crystalline state, six dimethylsulfoxide molecules are bound simultaneously in a nano-sized cavity via hydrogen bonds. (C) 2004 Elsevier Ltd. All rights reserved.

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