Journal
ORGANIC LETTERS
Volume 6, Issue 11, Pages 1809-1812Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol049464i
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The Cul-catalyzed coupling reaction of vinyl halides with amides or carbamates proceeds well at room temperature to 80 degreesC in dioxane to give enamides using NN-dimethylglycine as the promoter and Cs2CO3 as the base. The geometry of the C-C double bond is retained during the reaction course.
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