Journal
ORGANIC LETTERS
Volume 6, Issue 11, Pages 1861-1864Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0493711
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The combined use of chiral Pd complex 2 and amine salt enabled completely regulated release of free nucleophilic amine. Under these conditions, an efficient catalytic asymmetric conjugate addition of various amines was achieved to afford beta-amino acid derivatives in high chemical yields with up to 98% ee. Furthermore, a highly enantioselective protonation in 1,4-addition of amine was also developed.
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