Journal
ORGANIC LETTERS
Volume 6, Issue 11, Pages 1869-1871Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0493406
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- NIGMS NIH HHS [GM 35727] Funding Source: Medline
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Treatment of 2-(phenylsulfinyl)indoles bearing a pendant nucleophile at C(3) with Tf2O/lutidine triggers a Pummerer-like cyclization to furnish 3,3-spirocyclic-2-(phenyithio)indolenine products, which can, in turn, be hydrolyzed to 3,3-spirocyclic oxindoles.
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