Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 69, Issue 11, Pages 3774-3781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo040127x
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- NIGMS NIH HHS [GM 57870] Funding Source: Medline
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Five-, six-, and seven-membered cyclic alpha-amino phosphonates, amino acid surrogates, are prepared in enantiomerically pure form via the highly diastereomeric addition of metal phosphonates to masked oxo sulfinimines. Hydrolysis of the resulting masked oxo alpha-amino phosphonates followed by reduction of the intermediate cyclic imino phosphonates affords the title compounds in good yield.
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