Journal
TETRAHEDRON
Volume 60, Issue 23, Pages 5111-5115Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.03.094
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The efficient asymmetric synthesis of the antifungal pyrrolidine alkaloid (+)-preussin (2) was accomplished via the stereoselective reduction of a 5-substituted 3-oxo proline. The oxo proline was prepared from an N-sulfinyl delta-amino beta-ketoester, a sulfinimine derived polyfunctionalized chiral building block. (C) 2004 Elsevier Ltd. All rights reserved.
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