Journal
MAGNETIC RESONANCE IN CHEMISTRY
Volume 42, Issue 6, Pages 534-555Publisher
WILEY
DOI: 10.1002/mrc.1368
Keywords
NMR; F-19 NMR; H-1 NMR; C-13 NMR; F-19-F-19 coupling constants; F-19-H-1 coupling constants; H-1-H-1 coupling constants; long-range coupling; F-19-F-19 correlation 2D NMR; Cl-35,Cl-37 isotope effects; solvent effects; halocarbons
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F-19 NMR chemical shifts and coupling constants are reported for 215 compounds. For 77 of these compounds, H-1 NMR spectral data are also given. Long-range couplings, including (8)J(F,F) and (5)J(F,H), are reported. The complexity of halocarbon spectra owing to the presence of rotational isomers, asymmetric centers, long-range couplings, and chlorine isotope effects are illustrated, and the methods used for analyzing such complex spectra are briefly discussed. Copyright (C) 2004 John Wiley Sons, Ltd.
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