Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 6, Pages 770-772Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2004.04.012
Keywords
electronic spectra; photoluminescence; gadolinium compounds; chromium complexes; cobalt complexes
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Gadolinium induces a heavyatom effect in the complexes [M(CN)(6)](3-) with M=Cr and Co. As a consequence the compounds Gd[M(CN)(6)] show an intense phosphorescence from dd states under ambient conditions. (C) 2004 Elsevier B.V. All rights reserved.
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