Journal
NATURAL PRODUCT REPORTS
Volume 21, Issue 3, Pages 321-352Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b305068h
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Recent studies on enzymes catalyzing the Diels-Alder reaction, often named Diels-Alderases, clearly demonstrated the involvement of this synthetically useful reaction in the biosynthesis of natural products. This review covers natural Diels-Alder type cycloadducts, synthetic efforts on the chemical feasibility of the biosynthetic Diels-Alder reaction and a brief history of studies on Diels-Alderases. In addition, reaction mechanisms of artificial and natural Diets-Alderases are discussed.
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