4.8 Article

Carbon-nanotube-templated and pseudorotaxane-formation-driven gold nanowire self-assembly

Journal

CHEMISTRY OF MATERIALS
Volume 16, Issue 11, Pages 2174-2179

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cm035368k

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A cation-modified multiwalled carbon nanotube is used to template the noncovalent selfassembly in solution of a gold nanowire from crown-modified gold nanoparticles. The driving force for self-assembly is formation of the surface-confined pseudorotaxane that results from the electron-poor cation threading the electron-rich crown.

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