Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 7, Pages 737-741Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404020
Keywords
chirality; circular dichroism; helical structures; structure elucidation; transition metals
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The first example of the pentadentate bis(oxazolines) has been synthesized using a modular approach that readily provides access to this ligand class. This ligand allows the controlled transfer of carbon-centered to octahedral, metal-centered chirality, as demonstrated both in the solid state as well as in solution. The characteristic CD band has been identified for dicationic, octahedral transition metal complexes with the Delta(2)-configuration.
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