4.4 Article

Heterogeneous shvo-type ruthenium catalyst: dehydrogenation of alcohols without hydrogen acceptors

Journal

TETRAHEDRON LETTERS
Volume 45, Issue 24, Pages 4607-4610

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.04.113

Keywords

silica sol-gel; diruthenium; dehydrogenation alcohols

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A Shvo-type diruthenium complex is heterogenized by a sol-gel process, which catalyzes the conversion of alcohols to carbonyl compounds and molecular hydrogen without any additive. The heterogeneous catalyst is recoverable by simple filtration, stable in the air, and reusable. (C) 2004 Elsevier Ltd. All rights reserved.

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